An open metal site metal–organic framework Cu(BDC) as a promising heterogeneous catalyst for the modified Friedländer reaction

Authors: Nam T.S. Phan, Tung T. Nguyen, Khoa D. Nguyen, Anh X.T. Vo

Abstract:
A crystalline porous metal–organic framework Cu(BDC) was synthesized, and characterized by several techniques, including X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), Fourier transform infrared (FT-IR), atomic absorption spectrophotometry (AAS), hydrogen temperature-programmed reduction (H2-TPR), and nitrogen physisorption measurements. The Cu(BDC) exhibited high catalytic activity for the modified Friedländer transformation using 2-aminobenzyl alcohol as the starting material, thus offering advantages over the conventional Friedländer reaction in terms of avoiding the problems associated with the storage of the highly unstable 2-aminobenzaldehyde. Moreover, the Cu(BDC) could offer significantly higher catalytic activity than that of other Cu-MOFs such as Cu3(BTC)2, Cu(BPDC), and Cu2(BDC)2(DABCO). The catalyst could be recovered and reused several times without a significant degradation in catalytic activity. The modified Friedländer reaction could only occur in the presence of the solid Cu(BDC) with no contribution from leached active species.

Keywords:
Metal–organic framework
Friedländer reaction
Quinoline
Heterogeneous catalyst
Cu(BDC)

Published in: Applied catalysis A: General  (Volumes 464–465, Pages 1-384, 15 August 2013)

Publisher: Elsevier  

ISSN Information: 0926-860X

An open metal site metal–organic framework Cu(BDC) as a promising heterogeneous catalyst for the modified Friedländer reaction

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