Carbon nitride-catalyzed oxidative cleavage of carbon–carbon bond of α-hydroxy ketones with visible light and thermal radiation

Authors: Haiying Zhan, Wenjie Liu, Minling Fu, Jinghe Cen, Jingxin Lin, Hua Cao

Abstract:
Mesoporous carbon nitride (mpg-C₃N₄) as a photocatalyst showed higher photocatalytic activities in organic synthesis. Herein we reported a mpg-C₃N₄-catalyzed oxidation of α-hydroxy ketones to synthesize benzoic acids with visible light. This reaction represented a green and facile route to synthesize benzoic acids for which catalytic approaches were scarce.

Keywords:
Carbon nitride
Oxidation cleavage
α-Hydroxy ketones
Visible light
Benzoic acid

Published in: Applied catalysis A: General   (Volume 468, Pages 1-474, 5 November 2013)

Publisher: Elsevier  

ISSN Information: 0926-860X

Carbon nitride-catalyzed oxidative cleavage of carbon–carbon bond of α-hydroxy ketones with visible light and thermal radiation

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