Iron oxide functionalised MIL-101 materials in aqueous phase selective oxidations

Authors:  Alina Mariana Balu, Carol Sze Ki Lin, Hongli Liu, Yingwei Li, Carolina Vargas, Rafael Luque

Abstract:
A highly active Fe containing MIL-101 material has been prepared by using a simple microwave-assisted deposition methodology. The material, characterized by several techniques including N₂ physisorption, XPS and TEM, was found to have a significantly enhanced acidity due to the incorporation of ca. 2 wt.% Fe in the form of hematite Fe₂O₃ phase. Fe/MIL-101 exhibited excelling activities in aqueous phase oxidations of alcohols and alkenes using hydrogen peroxide as green oxidant.

Keywords:
Heterogeneous catalysis
Metal-organic frameworks
Microwave chemistry
Nanoparticles
Oxidation

Published in: Applied catalysis A: General  (Volume 455, Pages 1-266, 30 March 2013)

Publisher: Elsevier

ISSN Information: 0926-860X

Iron oxide functionalised MIL-101 materials in aqueous phase selective oxidations

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