Oxidative coupling of methane to C2 hydrocarbons on the Mg–Ti mixed oxide-supported catalysts at the lower reaction temperature: Role of surface oxygen atoms

Authors: Wonjin Jeon, Jong Yeol Lee, Maro Lee, Jae-Wook Choi, Jeong-Myeong Ha, Dong Jin Suh, Il Won Kim

Abstract:
The oxidative coupling of methane (OCM) couples methane molecules, which are the major components of natural gas, to form ethane and ethylene in order to produce fuels and chemicals. Because of the high reaction temperature (700–900^◦C) to obtain high yields of desirable products, the OCM process has been difficult to commercialize. We have developed a less energy-intensive OCM process that exhibits higher activity at a lower reaction temperature using Mg–Ti mixed oxide-supported Na/W/Mn catalysts. The catalyst consisting ofMg/(Mg + Ti) = 0.5 (mol/mol) exhibited thehighest C₂ hydrocarbons yields (i.e., 18.1% at 825 ◦C and 16.5% at 775^◦C) among the mixed oxide-supported catalysts, which were higher than those of the conventional SiO₂-supported catalyst particularly at a low temperature of 775^◦C (12.8%). Based on catalyst characterization by transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), UV–vis spectroscopy (UV–vis), O₂-temperature programmed desorption (O2-TPD), and CO₂-temperature programmed desorption (CO₂-TPD), the improved catalytic activity of the mixed oxide-supported catalysts was attributed to more active surface lattice O atoms. 

Keywords:
Oxidative coupling of methane
Mg–Ti mixed oxide
Catalyst
Surface lattice oxygen

Published in: Applied catalysis A: General  (Volumes 464–465, Pages 1-384, 15 August 2013)

Publisher: Elsevier  

ISSN Information: 0926-860X

Oxidative coupling of methane to C2 hydrocarbons on the Mg–Ti mixed oxide-supported catalysts at the lower reaction temperature: Role of surface oxygen atoms

Bình luận của bạn

*

*

*

*

 Captcha

Gửi bình luận nhập lại