Oxidative desulfurization of diesel with oxygen: Reaction pathways on supported metal and metal oxide catalysts
Authors: Kerry M. Dooley, Dongxing Liu, Andrew M. Madrid, F. Carl Knopf
Abstract:
We examined oxidative desulfurization (ODS) of a model diesel under conditions where O2 is the oxidant. To help understand the overall reaction pathways, we focused on all oxidation reactions in the system, including those of the alkylaromatic and nitrogen heterocycle components of the diesel. Three catalyst classes were studied in particular: supported Pd (on activated carbons or alumina), supported metal carbides and mesoporous titanium silicates. It is shown that regardless of catalyst the reaction rate for ODS is heavily influenced by the other oxidizable components present, especially the alkylaromatics. These compounds are oxidized to a greater extent than the sulfur heterocycles (by almost an order of magnitude on a molar basis), and temperatures must be kept less than 100 ◦C in order to minimize co-oxidation. Attaining a measurable rate at these temperatures requires high O2 partial pressures and therefore higher pressure than typically used for peroxide-based oxidations. The products formed from the oxidation of some typical alkylaromatics and nitrogen heterocycles were determined. These products suggest the same reaction pathways are present regardless of oxidant, and over a wide range of catalysts. The results strongly suggestthat a key step in the oxidation of sulfur heterocycles with O2 is the generation of hydroperoxides from alkylaromatics and similar oxidizable hydrocarbons; it is these hydroperoxides which in turn oxidize the heterocycles.
Keywords:
Oxidative desulfurization
Alkylaromatic oxidation
Palladium
Molybdenum carbide
Titanium silicate
Published in: Applied catalysis A: General (Volume 468, Pages 1-474, 5 November 2013)
Publisher: Elsevier
ISSN Information: 0926-860X
Oxidative desulfurization of diesel with oxygen: Reaction pathways on supported metal and metal oxide catalysts
- Vòng Sơ Khảo Cuộc Thi Đại Sứ Văn Hóa Đọc Năm 2024
- Ngày hội sách “CITTADELLA” khuyến khích và tôn vinh vai trò của sách trong sinh viên Bách khoa
- Cuộc Thi Ảnh “Khoảnh Khắc VNUHCM Libraries”
- Ngày hội Văn hóa đọc lần VI
- Ngày hội văn hóa đọc lần V
- Ngày hội văn hóa đọc lần II
- Ngày hội văn hóa đọc lần IV
- Ngày hội văn hóa đọc lần III
- Tiếp GS Omer Mert Denizci, Trường ĐH Marmara Thổ Nhĩ Kỳ
- Tiếp Cô Claudia Tarzariol Từ The University Of Trento, Italy (Unitrento)
- Tiến sĩ kiều bào Mỹ tặng sách trị giá 150.000 USD cho sinh viên bách khoa
- Khảo sát ý kiến bạn đọc
-
Trực tuyến:35
-
Hôm nay:3269
-
Tuần này:6032
-
Tuần trước:35602
-
Tháng trước:38871
-
Tất cả:4060767