Visible light-driven aerobic oxidation catalyzed by a diiron(IV) μ-oxo biscorrole complex

Authors:  Rui Zhang, Eric Vanover, Tse-Hong Chen, Helen Thompson

Abstract:
Under visible light irradiation, the diiron(IV) -oxo-bis(5,10,15-tripentafluorophenylcorrole) complex catalyzes the aerobic oxidations of hydrocarbons in sequences employing photo-disproportionation reactions. The active oxidant, highly reactive corrole-iron(V)-oxo species, can be detected in realtime via laser flash photolysis methods.

Keywords:
Iron corrole
Aerobic oxidation
Visible light
Photo-disproportionation

Published in: Applied catalysis A: General  (Volumes 464–465, Pages 1-384, 15 August 2013)

Publisher: Elsevier  

ISSN Information: 0926-860X

Visible light-driven aerobic oxidation catalyzed by a diiron(IV) μ-oxo biscorrole complex

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